Chapter 20
Nonmetallic Elements
By Boundless
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Hydrogen is the smallest element, with one proton and one electron. It is highly abundant and has unique and important chemical properties.
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Hydrides are compounds in which one or more hydrogen anions have nucleophilic, reducing, or basic properties.
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Hydrogen has three naturally occurring isotopes: protium, deuterium and tritium. Each isotope has different chemical properties.
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Hydrogenation reactions, which involve the addition of hydrogen to substrates, have many important applications.
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The hydrogen economy refers to using hydrogen as the next important source of fuel.
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Boron is produced by cosmic ray spallation, is a metalloid, and is essential to life.
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When in a compound with halides, boron has the formal oxidation state +3. Trihalides adopt a planar trigonal structure and are Lewis acids.
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Oxoanions that contain boron are called borates.
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Boranes are chemical compounds of boron and hydrogen with general formula BxHy; many readily oxidize on contact with air.
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Carbon has very diverse physical and chemical properties due to the nature of its bonding.
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Carbides are a class of compounds composed of carbon and an electropositive atom.
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Oxocarbons are compounds containing carbon and oxygen; they exist as carbon oxides and carbonates.
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Various allotropes of carbon exhibit different properties and find applications in a variety of fields.
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The basic unit of silicate, [SiO4]4- tetrahedron, can form single and double chains and sheets.
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Glass is a non-crystalline solid material made of silica, while quartz is a crystalline silicate mineral with piezoelectric properties.
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Aluminosilicate minerals are composed of aluminum, silicon, and oxygen.
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Nitrogen in its elemental form is a non-metallic gas that makes up 78 percent of Earth's atmosphere.
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Nitrogen compounds, and especially their oxidized derivatives, are important in biological systems and as explosives.
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Phosphorus is found in its elemental form as different allotropes, none of which are stable in the presence of oxygen.
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Phosphorus compounds consist mostly of compounds containing strong phosphorus-oxygen bonds. They are important in fertilizers and biology.
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Oxygen is a highly reactive nonmetallic element; it is a strong oxidizing agent with high electronegativity and forms O2 at Standard Temperature and Pressure (STP).
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An oxide is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula.
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Oxygen is essential for all aerobic organisms; common medical uses include oxygen therapy, hyperbaric medicine, and space suits.
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Ozone (O3) is diamagnetic (its electrons are all paired) and is a powerful oxidant.
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Halogens (fluorine, chlorine, bromine, iodine, astatine) are nonmetal elements that are highly electronegative and reactive.
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Halogens are highly reactive and can form hydrogen halides, metal halides, organic halides, interhalogens, and polyhalogenated compounds.
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Although halogens and their compounds can be toxic, some are essential for the human body's functioning and are used in everyday products.