Chapter 29 Appendix E: Standard Reduction Potentials at 25°C

Half-Reaction E° (V)
Ac3+ + 3e−→ Ac −2.20
Ag+ + e−→ Ag 0.7996
AgBr + e−→ Ag + Br− 0.07133
AgCl + e−→ Ag + Cl− 0.22233
Ag2CrO4 + 2e−→ 2Ag + CrO42− 0.4470
AgI + e−→ Ag + I− −0.15224
Ag2S + 2e−→ 2Ag + S2− −0.691
Ag2S + 2H+ + 2e−→ 2Ag + H2S −0.0366
AgSCN + e−→ Ag + SCN− 0.08951
Al3+ + 3e−→ Al −1.662
Al(OH)4− + 3e−→ Al + 4OH− −2.328
Am3+ + 3e−→ Am −2.048
As + 3H+ + 3e−→ AsH3 −0.608
H3AsO4 + 2H+ + 2e−→ HAsO2 + 2H2O 0.560
Au+ + e−→ Au 1.692
Au3+ + 3e−→ Au 1.498
H3BO3 + 3H+ + 3e−→ B + 3H2O −0.8698
Ba2+ + 2e−→ Ba −2.912
Be2+ + 2e−→ Be −1.847
Bi3+ + 3e−→ Bi 0.308
BiO+ + 2H+ + 3e−→ Bi + H2O 0.320
Br2(aq) + 2e−→ 2Br− 1.0873
Br2(l) + 2e−→ 2Br− 1.066
BrO3− + 6H+ + 5e−→ 12Br2 + 3H2O 1.482
BrO3− + 6H+ + 6e−→ Br− + 3H2O 1.423
CO2 + 2H+ + 2e−→ HCO2H −0.199
Ca2+ + 2e−→ Ca −2.868
Ca(OH)2 + 2e−→ Ca + 2OH− −3.02
Cd2+ + 2e−→ Cd −0.4030
CdSO4 + 2e−→ Cd + SO42− −0.246
Cd(OH)42− + 2e−→ Cd + 4OH− −0.658
Ce3+ + 3e−→ Ce −2.336
Ce4− + e−→ Ce3+ 1.72
Cl2(g) + 2e−→ 2Cl− 1.35827
HClO + H+ + e−→ 12Cl2 + H2O 1.611
HClO + H+ + 2e−→ Cl− + H2O 1.482
ClO− + H2O + 2e−→ Cl− + 2OH− 0.81
ClO3− + 6H+ + 5e−→ 12Cl2 + 3H2O 1.47
ClO3− + 6H+ + 6e−→ Cl− + 3H2O 1.451
ClO4− + 8H+ + 7e−→ 12Cl2 + 4H2O 1.39
ClO4− + 8H+ + 8e−→ Cl− + 4H2O 1.389
Co2+ + 2e−→ Co −0.28
Co3+ + e−→ Co2+ 1.92
Cr2+ + 2e−→ Cr −0.913
Cr3+ + e−→ Cr2+ −0.407
Cr3+ + 3e−→ Cr −0.744
Cr2O7− + 14H+ + 6e−→ 2Cr3+ + 7H2O 1.232
CrO42− + 4H2O + 3e−→ Cr(OH)3 + 5OH− −0.13
Cs+ + e−→ Cs −3.026
Cu+ + e−→ Cu 0.521
Cu2+ + e−→ Cu+ 0.153
Cu2+ + 2e−→ Cu 0.3419
CuI2− + e−→ Cu + 2I− 0.00
Cu2O + H2O + 2e−→ 2Cu + 2OH− −0.360
Dy3+ + 3e−→ Dy −2.295
Er3+ + 3e−→ Er −2.331
Es3+ + 3e−→ Es −1.91
Eu2+ + 2e−→ Eu −2.812
Eu3+ + 3e−→ Eu −1.991
F2 + 2e−→ 2F− 2.866
Fe2+ + 2e−→ Fe −0.447
Fe3+ + 3e−→ Fe −0.037
Fe3+ + e−→ Fe2+ 0.771
[Fe(CN)6]3− + e−→ [Fe(CN)6]4− 0.358
Fe(OH)3 + e−→ Fe(OH)2 + OH− −0.56
Fm3+ + 3e−→ Fm −1.89
Fm2+ + 2e−→ Fm −2.30
Ga3+ + 3e−→ Ga −0.549
Gd3+ + 3e−→ Gd −2.279
Ge2+ + 2e−→ Ge 0.24
Ge4+ + 4e−→ Ge 0.124
2H+ + 2e−→ H2 0.00000
H2 + 2e−→ 2H− −2.23
2H2O + 2e−→ H2 + 2OH− −0.8277
H2O2 + 2H+ + 2e−→ 2H2O 1.776
Hf4+ + 4e−→ Hf −1.55
Hg2+ + 2e−→ Hg 0.851
2Hg2+ + 2e−→ Hg22+ 0.920
Hg2Cl2 + 2e−→ 2Hg + 2Cl− 0.26808
Ho2+ + 2e−→ Ho −2.1
Ho3+ + 3e−→ Ho −2.33
I2 + 2e−→ 2I− 0.5355
I3− + 2e−→ 3I− 0.536
2IO3− + 12H+ + 10e−→ I2 + 6H2O 1.195
IO3− + 6H+ + 6e−→ I− + 3H2O 1.085
In+ + e−→ In −0.14
In3+ + 2e−→ In+ −0.443
In3+ + 3e−→ In −0.3382
Ir3+ + 3e−→ Ir 1.156
K+ + e−→ K −2.931
La3+ + 3e−→ La −2.379
Li+ + e−→ Li −3.0401
Lr3+ + 3e−→ Lr −1.96
Lu3+ + 3e−→ Lu −2.28
Md3+ + 3e−→ Md −1.65
Md2+ + 2e−→ Md −2.40
Mg2+ + 2e−→ Mg −2.372
Mn2+ + 2e−→ Mn −1.185
MnO2 + 4H+ + 2e−→ Mn2+ + 2H2O 1.224
MnO4− + 8H+ + 5e−→ Mn2+ + 4H2O 1.507
MnO4− + 2H2O + 3e−→ MnO2 + 4OH− 0.595
Mo3+ + 3e−→ Mo −0.200
N2 + 2H2O + 6H+ + 6e−→ 2NH4OH 0.092
HNO2 + H+ + e−→ NO + H2O 0.983
NO3− + 4H+ + 3e−→ NO + 2H2O 0.957
Na+ + e−→ Na −2.71
Nb3+ + 3e−→ Nb −1.099
Nd3+ + 3e−→ Nd −2.323
Ni2+ + 2e−→ Ni −0.257
No3+ + 3e−→ No −1.20
No2+ + 2e−→ No −2.50
Np3+ + 3e−→ Np −1.856
O2 + 2H+ + 2e−→ H2O2 0.695
O2 + 4H+ + 4e−→ 2H2O 1.229
O2 + 2H2O + 2e−→ H2O2 + 2OH− −0.146
O3 + 2H+ + 2e−→ O2 + H2O 2.076
OsO4 + 8H+ + 8e−→ Os + 4H2O 0.838
P + 3H2O + 3e−→ PH3(g) + 3OH− −0.87
PO43− + 2H2O + 2e−→ HPO32− + 3OH− −1.05
Pa3+ + 3e−→ Pa −1.34
Pa4+ + 4e−→ Pa −1.49
Pb2+ + 2e−→ Pb −0.1262
PbO + H2O + 2e−→ Pb + 2OH− −0.580
PbO2 + SO42− + 4H+ + 2e−→ PbSO4 + 2H2O 1.6913
PbSO4 + 2e−→ Pb + SO42− −0.3588
Pd2+ + 2e−→ Pd 0.951
Pm3+ + 3e−→ Pm −2.30
Po4+ + 4e−→ Po 0.76
Pr3+ + 3e−→ Pr −2.353
Pt2+ + 2e−→ Pt 1.18
[PtCl4]2− + 2e−→ Pt + 4Cl− 0.755
Pu3+ + 3e−→ Pu −2.031
Ra2+ + 2e−→ Ra −2.8
Rb+ + e−→ Rb −2.98
Re3+ + 3e−→ Re 0.300
Rh3+ + 3e−→ Rh 0.758
Ru3+ + e−→ Ru2+ 0.2487
S + 2e−→ S2− −0.47627
S + 2H+ + 2e−→ H2S(aq) 0.142
2S + 2e−→ S22− −0.42836
H2SO3 + 4H+ + 4e−→ S + 3H2O 0.449
SO42− + H2O + 2e−→ SO32− + 2OH− −0.93
Sb + 3H+ + 3e−→ SbH3 −0.510
Sc3+ + 3e−→ Sc −2.077
Se + 2e−→ Se2− −0.924
Se + 2H+ + 2e−→ H2Se −0.082
SiF62− + 4e−→ Si + 6F− −1.24
Sm3+ + 3e−→ Sm −2.304
Sn2+ + 2e−→ Sn −0.1375
Sn4+ + 2e−→ Sn2+ 0.151
Sr2+ + 2e−→ Sr −2.899
Ta3+ + 3e−→ Ta −0.6
TcO4− + 4H+ + 3e−→ TcO2 + 2H2O 0.782
TcO4− + 8H+ + 7e−→ Tc + 4H2O 0.472
Tb3+ + 3e−→ Tb −2.28
Te + 2e−→ Te2− −1.143
Te4+ + 4e−→ Te 0.568
Th4+ + 4e−→ Th −1.899
Ti2+ + 2e−→ Ti −1.630
Tl+ + e−→ Tl −0.336
Tl3+ + 2e−→ Tl+ 1.252
Tl3+ + 3e−→ Tl 0.741
Tm3+ + 3e−→ Tm −2.319
U3+ + 3e−→ U −1.798
VO2+ + 2H+ + e−→ VO2+ + H2O 0.991
V2O5 + 6H+ + 2e−→ 2VO2+ + 3H2O 0.957
W2O5 + 2H+ + 2e−→ 2WO2 + H2O −0.031
XeO3 + 6H+ + 6e−→ Xe + 3H2O 2.10
Y3+ + 3e−→Y −2.372
Yb3+ + 3e−→Yb −2.19
Zn2+ + 2e−→ Zn −0.7618
Zn(OH)42− + 2e−→ Zn + 4OH− −1.199
Zn(OH)2 + 2e−→ Zn + 2OH− −1.249
ZrO2 + 4H+ + 4e−→ Zr + 2H2O −1.553
Zr4+ + 4e−→ Zr −1.45